Publication Date

11-14-2022

Journal

Chemical Society Reviews

DOI

10.1039/d2cs00362g

PMID

36285735

PMCID

PMC9669245

PubMedCentral® Posted Date

11-14-2023

PubMedCentral® Full Text Version

Author MSS

Published Open-Access

yes

Keywords

Proteolysis, Ubiquitin-Protein Ligases, Drug Discovery

Abstract

Proteolysis-targeting chimeras (PROTACs) and targeted covalent inhibitors (TCIs) are currently two exciting strategies in the fields of chemical biology and drug discovery. Extensive research in these two fields has been conducted, and significant progress in these fields has resulted in many clinical candidates, some of which have been approved by FDA. Recently, a novel concept termed covalent PROTACs that combine these two strategies has emerged and gained an increasing interest in the past several years. Herein, we briefly review and highlight the mechanism and advantages of TCIs and PROTACs, respectively, and the recent development of covalent PROTACs using irreversible and reversible covalent chemistry.

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